Angelina Jolie's 15 Most Memorable Red Carpet Looks

Before she became a bona fide big-screen star, Angelina Jolie was known for the edgy ensembles she wore to movie premieres. As the natural beauty has matured, so has her sense of style. Before you head to the theater this weekend to see her in Salt, take a look at the A-lister's 15 most memorable red carpet looks.

15. Salt LA premiere (2010) At the Monday night premiere of her new spy flick, Angelina wowed the crowd in a sequined Emporio Armani strapless mini, sexy Salvatore Ferragamo heels, and a simple yet chic Asprey bracelet.

14. Taking Lives LA premiere (2004) The big screen beauty -- who rarely wears anything but basic black -- showed off her gorgeous gams in a skimpy, sand-colored Celine dress and gold Michael Kors pumps at the psychological thriller's debut.

13. British Academy of Film and Television Arts Awards (2009) Angie was back in black (and yellow) at the 62nd BAFTAs in a fabulous Armani Prive Spring 2009 frock, which featured a folded bodice and an interesting, mid-calf length.

12. 66th Annual Golden Globe Awards (2009) The mother of six looked effortlessly stylish upon arriving at the Beverly Hilton Hotel in a beautifully beaded Versace gown and softly tousled tresses.

11. 81st Annual Academy Awards (2009) The Oscar winner -- who was nominated for a second Academy Award for her work in 2008's "Changeling" -- was the epitome of elegance as she strutted down the red carpet in a sensationally sophisticated Elie Saab gown and emerald statement earrings, courtesy of Lorraine Schwartz.

10. 56th Annual Golden Globe Awards (1999) The then 24-year-old outshone her well-deserved trophy -- which she won for her work in the HBO made-for-TV movie, "Gia" -- in a bedazzled, champagne-colored halter dress and ruby red lips.

9. Inglourious Basterds LA premiere (2009) Brad's better half rocked the red carpet at the premiere of “Inglourious Basterds” in a $1,600 black leather Michael Kors masterpiece, which she paired with strappy Christian Dior stilettos.

8. 62nd Annual Cannes Film Festival Inglourious Basterds screening (2009) Mr. Pitt looked positively handsome in his Tom Ford tux, but it was Angelina who stole the spotlight in the South of France thanks to her glamorous chiffon Versace gown, caramel-colored coif, and signature smirk.

7. Lara Croft: Tomb Raider LA premiere (2001) It was, by no means, her best look, but one of Angelina's most memorable red carpet statements was made when she sported this painfully casual ensemble, consisting of a belly-baring tank and low-rise leather pants, to the "Tomb Raider" premiere in '01.

6. 60th Annual Cannes Film Festival Ocean's Thirteen premiere (2007) Fashion critics -- who had grown tired of seeing Angelina in nothing but black -- swooned when they saw the sultry star slink her way down the red carpet in Cannes in this yummy yellow Emanuel Ungaro gown.

5. 76th Annual Academy Awards (2004) South African visionary Marc Bouwer designed the plunging silk column gown and matching wrap Angelina donned to the 2004 Oscars. A pulled-back 'do and dripping diamond necklace completed her flawless look.

4. 15th Annual Screen Actors Guild Awards (2009) Angelina took a major fashion risk (that paid off) when she opted to wear this Max Azria dress -- which featured an elasticized waistband -- backwards, along with a loose updo, to the 15th Annual SAGs.

3. 72nd Annual Academy Awards (2000) Angie channeled her inner Elvira while getting gussied up in this goth Versace gown for the 72nd Annual Oscars, where she collected a Best Supporting Actress statue for her role in "Girl, Interrupted."

2. 61st Annual Cannes Film Festival Kung Fu Panda premiere (2008) Weeks before giving birth to twins, Knox and Vivienne, Angelina proudly showed off her baby bump in a mesmerizing Max Azria Atelier gown at the "Kung Fu Panda" premiere.

1. Mr. & Mrs. Smith LA premiere (2005) And, finally ... Angelina's most memorable red carpet look: the scandalously skintight, black leather Versace gown she wore to the highly anticipated premiere of "Mr. & Mrs. Smith," and which likely gives Jennifer Aniston nightmares to this day.